Material Information |
| Title: |
Microwave Spectroscopy of Mono-Substituted Benzenes at Room Temperature |
| Physical Description: |
Book |
| Language: |
English |
| Creator: |
Reinhold, Benjamin |
| Publisher: |
New College of Florida |
| Place of Publication: |
Sarasota, Fla. |
| Creation Date: |
2010 |
| Publication Date: |
2010 |
Subjects |
| Subjects / Keywords: |
Microwave Spectroscopy
Iodobenzene
Anisole
Fluorobenzene
Chirpec Pulse |
| Genre: |
bibliography ( marcgt )
theses ( marcgt )
government publication (state, provincial, terriorial, dependent) ( marcgt )
born-digital ( sobekcm )
Electronic Thesis or Dissertation |
Notes |
| Abstract: |
A significant challenge in room temperature microwave spectroscopy is the large number of transitions in a spectrum at 298 K. At these temperatures, multiple vibrational states are populated, each of which has its own distinct spectrum. Assignment of these spectra can be accomplished through a combination of experimental and computational techniques. Room temperature microwave spectra of fluorobenzene, iodobenzene, and anisole were collected and analyzed. For fluorobenzene the fit parameters for previously assigned states were refined. For iodobenzene, in addition to assigning new lines to transitions, the hyperfine terms for three excited states were resolved. Finally for anisole the fit parameters for previously assigned states were refined and two new preliminary fits were obtained. As a proof of principle, broadband 2-D measurements and narrowband double resonance measurements were made on iodobenzene. The implication of these measurement techniques for future spectral assignment are discussed. |
| Statement of Responsibility: |
by Benjamin Reinhold |
| Thesis: |
Thesis (B.A.) -- New College of Florida, 2010 |
| Electronic Access: |
RESTRICTED TO NCF STUDENTS, STAFF, FACULTY, AND ON-CAMPUS USE |
| Bibliography: |
Includes bibliographical references. |
| Source of Description: |
This bibliographic record is available under the Creative Commons CC0 public domain dedication. The New College of Florida, as creator of this bibliographic record, has waived all rights to it worldwide under copyright law, including all related and neighboring rights, to the extent allowed by law. |
| Local: |
Faculty Sponsor: Shipman, Steven |
Record Information |
| Source Institution: |
New College of Florida |
| Holding Location: |
New College of Florida |
| Rights Management: |
Applicable rights reserved. |
| Classification: |
local - S.T. 2010 R36 |
| System ID: |
NCFE004314:00001 |
|
Material Information |
| Title: |
Microwave Spectroscopy of Mono-Substituted Benzenes at Room Temperature |
| Physical Description: |
Book |
| Language: |
English |
| Creator: |
Reinhold, Benjamin |
| Publisher: |
New College of Florida |
| Place of Publication: |
Sarasota, Fla. |
| Creation Date: |
2010 |
| Publication Date: |
2010 |
Subjects |
| Subjects / Keywords: |
Microwave Spectroscopy
Iodobenzene
Anisole
Fluorobenzene
Chirpec Pulse |
| Genre: |
bibliography ( marcgt )
theses ( marcgt )
government publication (state, provincial, terriorial, dependent) ( marcgt )
born-digital ( sobekcm )
Electronic Thesis or Dissertation |
Notes |
| Abstract: |
A significant challenge in room temperature microwave spectroscopy is the large number of transitions in a spectrum at 298 K. At these temperatures, multiple vibrational states are populated, each of which has its own distinct spectrum. Assignment of these spectra can be accomplished through a combination of experimental and computational techniques. Room temperature microwave spectra of fluorobenzene, iodobenzene, and anisole were collected and analyzed. For fluorobenzene the fit parameters for previously assigned states were refined. For iodobenzene, in addition to assigning new lines to transitions, the hyperfine terms for three excited states were resolved. Finally for anisole the fit parameters for previously assigned states were refined and two new preliminary fits were obtained. As a proof of principle, broadband 2-D measurements and narrowband double resonance measurements were made on iodobenzene. The implication of these measurement techniques for future spectral assignment are discussed. |
| Statement of Responsibility: |
by Benjamin Reinhold |
| Thesis: |
Thesis (B.A.) -- New College of Florida, 2010 |
| Electronic Access: |
RESTRICTED TO NCF STUDENTS, STAFF, FACULTY, AND ON-CAMPUS USE |
| Bibliography: |
Includes bibliographical references. |
| Source of Description: |
This bibliographic record is available under the Creative Commons CC0 public domain dedication. The New College of Florida, as creator of this bibliographic record, has waived all rights to it worldwide under copyright law, including all related and neighboring rights, to the extent allowed by law. |
| Local: |
Faculty Sponsor: Shipman, Steven |
Record Information |
| Source Institution: |
New College of Florida |
| Holding Location: |
New College of Florida |
| Rights Management: |
Applicable rights reserved. |
| Classification: |
local - S.T. 2010 R36 |
| System ID: |
NCFE004314:00001 |
|