Material Information
- Title:
- CHIRPED-PULSE MICROWAVE SPECTROSCOPY OF SMALL MOLECULES
- Physical Description:
- Book
- Language:
- English
- Creator:
- McCabe, Morgan
- Publisher:
- New College of Florida
- Place of Publication:
- Sarasota, Fla.
- Publication Date:
- 2014
Thesis/Dissertation Information
- Degree:
- Bachelor's ( B.A.)
- Degree Grantor:
- New College of Florida
- Degree Divisions:
- Natural Sciences
- Area of Concentration:
- Chemistry
Subjects
- Genre:
- bibliography ( marcgt )
theses ( marcgt )
government publication (state, provincial, territorial, dependent) ( marcgt )
born-digital ( sobekcm )
Electronic Thesis or Dissertation
Notes
- Abstract:
- The microwave spectra of 3-methoxypropylamine, 2-aminobutanol, and allyl bromide
were recorded. The spectrum of allyl bromide was taken from 8.7-26.5 GHz at 253
K. The rotational spectrum of allyl bromide has been previously studied; however,
previous assignments only extended to J = 12 and Ka = 1 for the ground state and J
= 15 and Ka = 1 for vibrationally excited states. The fits were extended to J= 21 and
K a = 5, for the ground state and 2 vibrationally excited states. Additionally, the
spectra of methoxypropylamine and aminobutanol were taken on a molecular beam
instrument from 8.0-18.0 GHz at 2 K, due to issues with amine decomposition in
the waveguide. The rotational spectra of these molecules have not been previously
studied. The ground state spectrum was fit for both molecules, though, there are still
many lines left to assign in the methoxypropylamine spectrum. Finally, Gaussian
09 was used to find the lowest energy conformers for methoxypropylamine, ethoxy-
ethylamine, and aminobutanol, as well as to estimate rotational constants, distortion
constants, and hyperfine constants.
- Statement of Responsibility:
- by Morgan McCabe
- Thesis:
- Thesis (B.A.) -- New College of Florida, 2014
- General Note:
- RESTRICTED TO NCF STUDENTS, STAFF, FACULTY, AND ON-CAMPUS USE
- Bibliography:
- Includes bibliographical references.
- General Note:
- This bibliographic record is available under the Creative Commons CC0 public domain dedication. The New College of Florida Libraries, as creator of this bibliographic record, has waived all rights to it worldwide under copyright law, including all related and neighboring rights, to the extent allowed by law.
- General Note:
- Faculty Sponsor: Shipman, Steven
Record Information
- Source Institution:
- New College of Florida
- Holding Location:
- New College of Florida
- Rights Management:
- Applicable rights reserved.
- Resource Identifier:
- Classification:
- S.T. 2014 M433
- System ID:
- AA00024771:00001
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