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Partial Synthesis of Novel Ligands for the Catalytic Activation of Hydrogen Peroxide in Pursuit of Green Oxidative Chemistry

Permanent Link: http://ncf.sobek.ufl.edu/NCFE003946/00001

Material Information

Title: Partial Synthesis of Novel Ligands for the Catalytic Activation of Hydrogen Peroxide in Pursuit of Green Oxidative Chemistry
Physical Description: Book
Language: English
Creator: Kaplan, Daniel
Publisher: New College of Florida
Place of Publication: Sarasota, Fla.
Creation Date: 2008
Publication Date: 2008

Subjects

Subjects / Keywords: Catalytic Activation
Hydrogen Peroxide
Green Chemistry
Genre: bibliography   ( marcgt )
theses   ( marcgt )
government publication (state, provincial, terriorial, dependent)   ( marcgt )
born-digital   ( sobekcm )
Electronic Thesis or Dissertation

Notes

Abstract: Green chemistry, at its core, is about developing a chemically sustainable society. Water borne pollution is a growing concern throughout the world. As nations develop technologically, the potential for rapidly increasing pollution becomes a growing issue. A safe, clean, and reusable method for treating water must be developed. Hydrogen peroxide when catalytically activated by complexed high valent iron provides a powerful tool for treating and eliminating water borne pollution. Based off the natural model of cytochrome P450, an increasing number of synthetic ligands have been developed. This thesis details the development and partial synthesis of a novel ligand, designed to stabilize high valent iron for the catalytic activation of hydrogen peroxide. The final goal of this thesis is the physical attachment of the ligand for simplified extraction and reuse. A synthetic scheme was planned and then modified as necessary, when complications in synthesis arose. All but the final step of the synthesis was completed.
Statement of Responsibility: by Daniel Kaplan
Thesis: Thesis (B.A.) -- New College of Florida, 2008
Electronic Access: RESTRICTED TO NCF STUDENTS, STAFF, FACULTY, AND ON-CAMPUS USE
Bibliography: Includes bibliographical references.
Source of Description: This bibliographic record is available under the Creative Commons CC0 public domain dedication. The New College of Florida, as creator of this bibliographic record, has waived all rights to it worldwide under copyright law, including all related and neighboring rights, to the extent allowed by law.
Local: Faculty Sponsor: Scudder, Paul

Record Information

Source Institution: New College of Florida
Holding Location: New College of Florida
Rights Management: Applicable rights reserved.
Classification: local - S.T. 2008 K1
System ID: NCFE003946:00001

Permanent Link: http://ncf.sobek.ufl.edu/NCFE003946/00001

Material Information

Title: Partial Synthesis of Novel Ligands for the Catalytic Activation of Hydrogen Peroxide in Pursuit of Green Oxidative Chemistry
Physical Description: Book
Language: English
Creator: Kaplan, Daniel
Publisher: New College of Florida
Place of Publication: Sarasota, Fla.
Creation Date: 2008
Publication Date: 2008

Subjects

Subjects / Keywords: Catalytic Activation
Hydrogen Peroxide
Green Chemistry
Genre: bibliography   ( marcgt )
theses   ( marcgt )
government publication (state, provincial, terriorial, dependent)   ( marcgt )
born-digital   ( sobekcm )
Electronic Thesis or Dissertation

Notes

Abstract: Green chemistry, at its core, is about developing a chemically sustainable society. Water borne pollution is a growing concern throughout the world. As nations develop technologically, the potential for rapidly increasing pollution becomes a growing issue. A safe, clean, and reusable method for treating water must be developed. Hydrogen peroxide when catalytically activated by complexed high valent iron provides a powerful tool for treating and eliminating water borne pollution. Based off the natural model of cytochrome P450, an increasing number of synthetic ligands have been developed. This thesis details the development and partial synthesis of a novel ligand, designed to stabilize high valent iron for the catalytic activation of hydrogen peroxide. The final goal of this thesis is the physical attachment of the ligand for simplified extraction and reuse. A synthetic scheme was planned and then modified as necessary, when complications in synthesis arose. All but the final step of the synthesis was completed.
Statement of Responsibility: by Daniel Kaplan
Thesis: Thesis (B.A.) -- New College of Florida, 2008
Electronic Access: RESTRICTED TO NCF STUDENTS, STAFF, FACULTY, AND ON-CAMPUS USE
Bibliography: Includes bibliographical references.
Source of Description: This bibliographic record is available under the Creative Commons CC0 public domain dedication. The New College of Florida, as creator of this bibliographic record, has waived all rights to it worldwide under copyright law, including all related and neighboring rights, to the extent allowed by law.
Local: Faculty Sponsor: Scudder, Paul

Record Information

Source Institution: New College of Florida
Holding Location: New College of Florida
Rights Management: Applicable rights reserved.
Classification: local - S.T. 2008 K1
System ID: NCFE003946:00001

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